New Zealand Gold Prospecting & Metal Detecting Forums Archive

 

The forum has moved to community.paydirt.co.nz, see you there!

This forum is now an archive to preserve the knowledge and finds posted here.

number8wire  
Posted : Saturday, 6 July 2013 10:59:17 PM(UTC)
number8wire

Rank: Gold Ingot

Groups: Registered
Joined: 10/06/2012(UTC)
Posts: 1,175
Man
New Zealand
Location: Christchurch

Thanks: 913 times
Was thanked: 880 time(s) in 425 post(s)
Today I dug an old silver ring from North Hagley. It would have been around 8-9 inches deep. It appears to be extremely old but I cannot date it as it is not hallmarked. Normally when a silver coin is dug from this depth, it's usually in pretty-much the same condition it was dropped in. This ring however, shows obvious signs of silver degradation on the inner wall and around the rim.

My question is, would this degradation be an indication of the age of this silver?

I'm picking that this ring could well be early 1800's.........possibly even late 1700's manufacture. .....or even earlier than that???

Any ideas or clues welcomed that might either support or debunk this theory.

Edited by user Saturday, 6 July 2013 11:07:28 PM(UTC)  | Reason: Not specified

TEKNETICS T2 SE plus X-POINTER
2016
Silver coins- 233
Other silver- 13
Gold- 1
Sovereigns-0
Spendies -$119.00
Metal Kiwi  
Posted : Saturday, 6 July 2013 11:10:25 PM(UTC)
Metal Kiwi

Rank: Gold Ingot

Groups: Registered
Joined: 19/06/2011(UTC)
Posts: 1,210
Man
Location: Auckland

Thanks: 498 times
Was thanked: 484 time(s) in 322 post(s)
Unfortunately I dont think it is silver No 8 .
Looks homemade to me.

MK

Foiled again  
Posted : Saturday, 6 July 2013 11:14:17 PM(UTC)
Foiled again

Rank: Gold Ingot

Groups: Registered
Joined: 10/04/2012(UTC)
Posts: 861
Man
Location: Christchurch

Thanks: 459 times
Was thanked: 251 time(s) in 192 post(s)
Could it be one of those rings made from a coin?
There's another to find and I'm gunna find it!
number8wire  
Posted : Saturday, 6 July 2013 11:32:40 PM(UTC)
number8wire

Rank: Gold Ingot

Groups: Registered
Joined: 10/06/2012(UTC)
Posts: 1,175
Man
New Zealand
Location: Christchurch

Thanks: 913 times
Was thanked: 880 time(s) in 425 post(s)
Originally Posted by: Metal Kiwi Go to Quoted Post
Unfortunately I dont think it is silver No 8 .
Looks homemade to me.

MK



Thanks for your thoughts there MK but it is definitely old silver. I think yourself and foiled again may be on the right track tho with the home made theory.........although, I can't make out any obvious wording or graphics from any old silver coins I have seen.
TEKNETICS T2 SE plus X-POINTER
2016
Silver coins- 233
Other silver- 13
Gold- 1
Sovereigns-0
Spendies -$119.00
goldstalker  
Posted : Sunday, 7 July 2013 1:57:45 AM(UTC)
goldstalker

Rank: Gold Ingot

Groups: Registered
Joined: 11/10/2012(UTC)
Posts: 454
Location: greymouth, west coast

Thanks: 6 times
Was thanked: 67 time(s) in 57 post(s)
hi mate looks like the ring is silver plated and the inner metal has degraded faster than the silver plate ? looks old tho cool find ::)
Shilo  
Posted : Sunday, 7 July 2013 9:55:11 AM(UTC)
Shilo

Rank: Gold Ingot

Medals: Donation: Made a donation helping cover the running costs of the site - thank you :)

Groups: Registered
Joined: 29/01/2011(UTC)
Posts: 573
Location: Kawhia

Thanks: 17 times
Was thanked: 285 time(s) in 185 post(s)
I agree, it is unfortunately plated as it looks like the plating is coming off. It doesn't take long for this to happen in the soil.

UserPostedImage

Give it a scrub or a zap with electrolysis and the silver should peel off (don't worry it will only be about 1 cents worth) and show the base metal.
I have never seen a solid 925 ring "peel" like that, but all plated ones do. Instead solid silver normally "pits", the old ones are tarnished to a black or grey and the older they are the more pitted they become as the silver corrodes via the tarnish.

Edited by user Sunday, 7 July 2013 9:59:02 AM(UTC)  | Reason: Not specified

Lammerlaw  
Posted : Sunday, 7 July 2013 12:17:55 PM(UTC)
Lammerlaw

Rank: Gold Ingot

Groups: Registered
Joined: 24/05/2011(UTC)
Posts: 1,721

Thanks: 72 times
Was thanked: 579 time(s) in 396 post(s)

Your ring looks as though it is silver plated and the plating is peeling off.

I note the comments re the silver in the ground. There are three factors to take into account;-
1) - The purity. The purity of the silver from two perspectives, one being the actual silver content eg .925 etc and the second being poor grade alloy with impurities. The latter will not occur in professionally made pieces.
2) - The soil type. Two identical coins or rings might be lost on the same day but one in neutral or alkaline soil and one in highly acidic or salty soil. The ring lost in the latter soil type will corrode while the first one doesnt.
3) - Dampness. This factor can make corrosion more rapid so that two identical rings lost in the same soil, one damp site and one wet site will degrade at different rates, the ring or coin in the damp soil will degrade far more rapidly.

Aninteresting point that I noted now and again especially in conditions where there were trees and humus was to find a coin which was noticeably corroded, tarnished or stained on the top side and yet perfect on the side facing downward. I assumed this was the combined affect of a more effective seal against the soil on the downside and lighter compact soil on the topside and the fact that more water during rain would come into contact with the top side but this is just a 'sort of Intelligent' guess'
number8wire  
Posted : Sunday, 7 July 2013 8:34:40 PM(UTC)
number8wire

Rank: Gold Ingot

Groups: Registered
Joined: 10/06/2012(UTC)
Posts: 1,175
Man
New Zealand
Location: Christchurch

Thanks: 913 times
Was thanked: 880 time(s) in 425 post(s)
Hey, thanks for all the info guys. The pic is actually quite deceiving. What looks like "silver peel" is actually the high and low ridges of the inner core. The high ridges, which look like they could flake off are actually almost like "lumps" of silver and the low ridges are just as solid and shiny as the higher ridges but look darker in the pic because they are tarnished and dont clean up as readily as the high points. I have tried to capture the difference in differing light conditions but to no avail, as it always looks like plated peel.
I really believe it is probably an early Victorian (possibly earlier) silver coin that had been fashioned into a ring. Could also well be silver that had been melted down and put into a homemade ring mold. Either way, I am 100% sure it is solid ( poss .925) silver and not plated.
For any of the Chch guys that are interested, I'll bring it along to the next club meeting to see what you think.

Edited by user Sunday, 7 July 2013 8:40:30 PM(UTC)  | Reason: Not specified

TEKNETICS T2 SE plus X-POINTER
2016
Silver coins- 233
Other silver- 13
Gold- 1
Sovereigns-0
Spendies -$119.00
oroplata  
Posted : Sunday, 7 July 2013 8:59:59 PM(UTC)
oroplata

Rank: Gold Ingot

Groups: Registered, Moderators
Joined: 16/06/2011(UTC)
Posts: 1,040
Location: Christchurch

Thanks: 23 times
Was thanked: 211 time(s) in 152 post(s)

How much does it weigh, exactly?
number8wire  
Posted : Sunday, 7 July 2013 11:28:36 PM(UTC)
number8wire

Rank: Gold Ingot

Groups: Registered
Joined: 10/06/2012(UTC)
Posts: 1,175
Man
New Zealand
Location: Christchurch

Thanks: 913 times
Was thanked: 880 time(s) in 425 post(s)
Originally Posted by: oroplata Go to Quoted Post

How much does it weigh, exactly?


If you zoom in on the ring, you'll see that I have cleaned it up a bit more. The grey tarnish is slowly rubbing away to reveal more shiny silver beneath. I have been wearing the ring most of the day and revolving it on my finger to clean the interior tarnish.........and yes, it's silver and absolutely no peeling!

Edited by user Sunday, 7 July 2013 11:40:39 PM(UTC)  | Reason: Not specified

File Attachment(s):
TEKNETICS T2 SE plus X-POINTER
2016
Silver coins- 233
Other silver- 13
Gold- 1
Sovereigns-0
Spendies -$119.00
oroplata  
Posted : Monday, 8 July 2013 1:01:25 AM(UTC)
oroplata

Rank: Gold Ingot

Groups: Registered, Moderators
Joined: 16/06/2011(UTC)
Posts: 1,040
Location: Christchurch

Thanks: 23 times
Was thanked: 211 time(s) in 152 post(s)

Interesting. Close in weight to a sixpence. I wonder how accurate your scales are.

rgmcbrid  
Posted : Tuesday, 9 July 2013 6:29:01 PM(UTC)
rgmcbrid

Rank: Gold Ingot

Groups: Registered
Joined: 3/06/2010(UTC)
Posts: 583
Man
Location: Southland

Thanks: 23 times
Was thanked: 180 time(s) in 140 post(s)
Quote:
I note the comments re the silver in the ground. There are three factors to take into account;-
1) - The purity. The purity of the silver from two perspectives, one being the actual silver content eg .925 etc and the second being poor grade alloy with impurities. The latter will not occur in professionally made pieces.
2) - The soil type. Two identical coins or rings might be lost on the same day but one in neutral or alkaline soil and one in highly acidic or salty soil. The ring lost in the latter soil type will corrode while the first one doesnt.
3) - Dampness. This factor can make corrosion more rapid so that two identical rings lost in the same soil, one damp site and one wet site will degrade at different rates, the ring or coin in the damp soil will degrade far more rapidly.


I would add to this how much air it gets, more oxygen = more oxidation
oroplata  
Posted : Tuesday, 9 July 2013 6:57:21 PM(UTC)
oroplata

Rank: Gold Ingot

Groups: Registered, Moderators
Joined: 16/06/2011(UTC)
Posts: 1,040
Location: Christchurch

Thanks: 23 times
Was thanked: 211 time(s) in 152 post(s)

And let's not forget sulphur!

Lammerlaw  
Posted : Tuesday, 9 July 2013 7:29:06 PM(UTC)
Lammerlaw

Rank: Gold Ingot

Groups: Registered
Joined: 24/05/2011(UTC)
Posts: 1,721

Thanks: 72 times
Was thanked: 579 time(s) in 396 post(s)
Originally Posted by: rgmcbrid Go to Quoted Post
Quote:
I note the comments re the silver in the ground. There are three factors to take into account;-
1) - The purity. The purity of the silver from two perspectives, one being the actual silver content eg .925 etc and the second being poor grade alloy with impurities. The latter will not occur in professionally made pieces.
2) - The soil type. Two identical coins or rings might be lost on the same day but one in neutral or alkaline soil and one in highly acidic or salty soil. The ring lost in the latter soil type will corrode while the first one doesnt.
3) - Dampness. This factor can make corrosion more rapid so that two identical rings lost in the same soil, one damp site and one wet site will degrade at different rates, the ring or coin in the damp soil will degrade far more rapidly.


I would add to this how much air it gets, more oxygen = more oxidation


I thought of that when I was writing it and forgot to add it.

oroplata - generally speaking in New Zealand soil down here in the South there is very little sulphur - it is only when you get really deep down that you get the sulphur but by then it is pretty hot and you can hear little Imps chuckling gleefully as they fire more coals into the pits of Hades!

In the Northt Island there is a fair bit of sulphur in certain areas but then again I always did find certain areas of the North Island a veritable Hell hole!
Shilo  
Posted : Tuesday, 9 July 2013 7:43:25 PM(UTC)
Shilo

Rank: Gold Ingot

Medals: Donation: Made a donation helping cover the running costs of the site - thank you :)

Groups: Registered
Joined: 29/01/2011(UTC)
Posts: 573
Location: Kawhia

Thanks: 17 times
Was thanked: 285 time(s) in 185 post(s)
Surprisingly I don't think Sulpfur has much of an effect out of the laboratory. Being in Rotorua I dig in a lot of sulpfur enriched areas, including soil and hot pools and streams. Most of the corroded finds have come from stream and lake beds that have a lot of movement and the item gets worn more then corroded. Example is this morning I dug a large silver ring from under the Kerosene creek waterfall (hot and highly mineralised & sulpfuric water)- it was completely covered with a hard brown coating (I thought it was a junk ring at first) but after zapping came up fairly clean. Our modern steel cored coins get dissolved into nothing in this water.

To me Oxygen level has the greatest impact. The best preserved coins I have ever found came from very liquid smelly anaerobic mud - they looked brand new including pennies. The oxygen level of course is directly related to the amount of dampness that Lammerlaw mentioned as well.

Edited by user Tuesday, 9 July 2013 7:45:11 PM(UTC)  | Reason: Not specified